There is no a direct-correspondence to the famous F2 of Windows, but, it is possible to rename a file with fewer passages than the usual. Something very similar to a shortcut.

The traditional way is indeed:

select the folder/file – > right click on the folder or file -> rename

What you can do in a faster way is:

select the folder -> hold down FN and click

OR

select the folder -> click enter

That’s it! And you, do you know other methods?